Articles
  • Physical properties of the Sr4Al6O12SO4 ceramic compound
  • J.A. Rodríguez-Garcíaa, E. Rocha-Rangela,*, J. López Hernándeza, C.A. Hernández Bocanegraa, A.L. Leal Cruzb, J.M. Almanza Roblesc and J. Torres Torresc
  • a Universidad Politécnica de Victoria, Avenida Nuevas Tecnologías 5902, Parque Científico y Tecnológico de Tamaulipas, Cd. Victoria, Tamaulipas, México. 87138 b Universidad de Sonora, Departamento de Investigación en Física, Rosales y Luis Encinas, Hermosillo, Sonora, México, 85000 c CINVESTAV-Unidad Saltillo, Carretera Saltillo -Monterrey Km 13.5, Ramos Arizpe, Coahuila, México, 2590
Abstract
The Sr4Al6O12SO4 ceramic compound was synthesized by a solid state reaction starting from stoichiometric mixtures of 3 : 3 : 1 molar ratio of reactive grade of SrCO3, Al2O3 and SrSO4, respectively. Cylindrical samples were confirmed by uniaxial pressing at 100 MPa and were heat treated at 1400 oC during 4 hrs. Subsequently, the samples were ground and re-conformed in cylindrical shape samples by uniaxial pressing at 300 MPa. The new samples were heat treated at 1400 oC during 24 hrs. This process was done in order to increase density of the samples. The Sr4Al6O12SO4 ceramic compound was characterized by the study of its physical properties such as: density, micro-hardness, thermal expansion and stability, enthalpy of formation, magnetic properties and electrical conductivity. Experimental results show that the maximum density obtained for the Sr4Al6O12SO4 ceramic compound was 2.913 grcm−3, with thermal expansion coefficient of 10.12E−06(oC−1); it also presents an enthalpy of 2.3 KJmol-1 and an excellent thermal stability at elevated temperatures in different atmospheres. In addition, the Sr4Al6O12SO4 ceramic compound is neither electrically conductive nor magnetic.

Keywords: Physical properties, Strontium compound, Solid state reactions, Ceramic materials

This Article

  • 2017; 18(11): 801-804

    Published on Nov 30, 2017