Articles
  • Experimental and numerical investigation on in-flight synthesis of Ga-doped ZnO nano-powder by Radio-Frequency induction plasma
  • Jun-Seok Nama, Sang-Min Jeonga, Min-Gyu Choia, Jun-Ho Seoa,* and Shi-Young Yangb,*

  • aDepartment of Quantum System Engineering, Chonbuk National University, Jeonju 54896, Republic of Korea
    bGraduate School of Flexible & Printable Electronics, Chonbuk National University, Jeonju 54896, Republic of Korea

  • This article is an open access article distributed under the terms of the Creative Commons Attribution Non-Commercial License (http://creativecommons.org/licenses/by-nc/4.0) which permits unrestricted non-commercial use, distribution, and reproduction in any medium, provided the original work is properly cited.

Abstract

In this work, in-flight synthesis route of Ga doped ZnO (GZO) nano-powders was investigated experimentally and numerically, using Radio-Frequency (RF) induction plasmas. For experimental study, mixture of micron-sized ZnO and Ga2O3 powders were treated by RF induction plasmas, then, the as-treated powders were retrieved from reactor bottom and filtration for characterization. For numerical study, single particle model was combined with two-dimensional simulation code of RF induction plasma to predict the particle behaviors of ZnO and Ga2O3 depending on their sizes. First, experimental results showed that filtration-retrieved powders were characterized as GZO nano-powders although gallium content can be decreased due to Ga2O3 decomposition into sub-oxides at the elevated temperatures. From reactor bottom, however, spherical structures consisting of Ga2O3 and ZnO particles were observed in sub-millimeter sizes. Numerical results predicted that micron-sized (≤ 10 µm) ZnO and Ga2O3 particles can vaporize easily during the flight of plasma, while particles with the sizes of 25~100 um were simulated to be partially evaporated or unevaporated. Comparing these experimental and numerical results indicates that GZO nano-powders can be synthesized from vapor species of ZnO and Ga2O3, which are primarily produced by in-flight treatment of micron-sized ZnO and Ga2O3 powders in RF induction plasmas


Keywords: Ga doped ZnO, Radio-Frequency induction plasma, Numerical analysis, Nano powder, in-flight heat treatment

This Article

  • 2021; 22(2): 169-178

    Published on Apr 30, 2021

  • 10.36410/jcpr.2021.22.2.169
  • Received on Jul 28, 2020
  • Revised on Nov 1, 2020
  • Accepted on Nov 11, 2020

Correspondence to

  • Jun-Ho Seo a and Shi-Young Yang b
  • aDepartment of Quantum System Engineering, Chonbuk National University, Jeonju 54896, Republic of Korea
    bGraduate School of Flexible & Printable Electronics, Chonbuk National University, Jeonju 54896, Republic of Korea
    Tel: +82-63-270-4295 (Jun-Ho Seo)
    Tel: +82-63-270-2022 (Shi-Young Yang)

  • E-mail: jhseo@jbnu.ac.kr (Jun-Ho Seo), yangsy@jbnu.ac.kr (