Articles
  • Electrochemical characteristics of Tin-based anode material for Li-ion secondary batteries
  • Jangwon Oha, Kihyun Choa, Taewon Leea, Insoo Hwanga, Siyoul Jangb and Dongwook Shina,*
  • a Division of Materials Science and Engineering, Hanyang University, 17 Haengdang-dong, Seongdong-gu, Seoul, 133-791, Korea b School of Mechanical and Automotive Engineering, Kookmin University, Korea
Abstract
Recently tin-based composite oxide materials have received considerable attention as a negative electrode for lithium ion secondary batteries. In this study, nano-sized SnO2-B2O3-P2O5 particles were synthesized by an Aerosol Flame Deposition(AFD) technique. Single or multi-component amorphous oxide nano particles (soot) were synthesized by supplying metal halide sources such as chloride in the form of gas into an oxy-hydrogen flame. The fine powder obtained was a mixture of crystalline tin oxide and an amorphous phase of B2O3 and P2O5, resulting in a highly dispersed structure with nano-scale interfaces. According to the XRD results, the as-prepared materials seemed to have a semi-amorphous structure and SEM images showed that the average particle size <60 nm. In this study, we investigated the relationship between the structural modification of the tin-based composite oxide and the conductivity as a function of the composition.

Keywords: SnO2-B2O3-P2O5, Li-ion battery, Aerosol Flame Deposition, Anode materials.

This Article

  • 2008; 9(1): 52-56

    Published on Feb 28, 2008