Articles
  • Model-free kinetics applied to an oxidation mechanism of a biomorphic carbon template derived from pine 
  • Wenxiang Wang, Weiei Gong and Pengzhao Gao*
  • College of Materials Science and Engineering, Hunan University, Changsha 410082, P.R.China
Abstract
A biomorphic carbon template (BCT) was developed by carbonizing pine under vacuum. Structural and oxidation properties of BCT were evaluated by scanning electron microscopy (SEM), X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), and thermogravimetric analysis (TGA). Experimental results show that BCT has a topologically uniform interconnected porous network microstructure, and is typical non-graphitizable carbon containing C = C bonds, C-O-C bonds and a C H structure. The non-isothermal oxidation properties of BCT exhibit a partially self-accelerating characteristic; the oxidation process of BCT is firstly controlled by a chemical reaction, and then controlled by a chemical reaction and gas diffusion together, which is obtained from a Vyazovkin model-free method, and the corresponding activation energy (E) is also calculated.

Keywords: biomorphic carbon template; Vyazovkin model-free method; self-accelerating

This Article

  • 2010; 11(4): 508-512

    Published on Aug 31, 2010

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